SUMMARY OF PM7 CALCULATION, Site No: 23746 MOPAC2016 (Version: 21.055M) Thu Feb 25 05:21:53 2021 No. of days remaining = 364 Empirical Formula: O24 W8 = 32 atoms MERS=(1,1,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Tungsten(vi) trioxide (WO3) h=-201.4 hr=crc GEOMETRY OPTIMISED USING EIGENVECTOR FOLLOWING (EF). SCF FIELD WAS ACHIEVED HEAT OF FORMATION = -1578.59203 KCAL/MOL = -6604.82907 KJ/MOL H.o.F. per unit cell = -197.32400 KCAL, for 8 unit cells, unit cell = O3 W1 TOTAL ENERGY = -8641.52623 EV ELECTRONIC ENERGY = -21702290.08275 EV CORE-CORE REPULSION = 21693648.55652 EV VOLUME OF UNIT CELL = 469.840 CUBIC ANGSTROMS DENSITY = 6.555 GRAMS/CC A = 8.021 ANGSTROMS B = 7.745 ANGSTROMS C = 7.564 ANGSTROMS ALPHA = 89.533 DEGREES BETA = 89.945 DEGREES GAMMA = 90.042 DEGREES GRADIENT NORM = 3.67269 = 0.64925 PER ATOM NO. OF FILLED LEVELS = 96 IONIZATION POTENTIAL = 11.998948 EV HOMO LUMO ENERGIES (EV) = -11.999 -1.187 MOLECULAR WEIGHT = 1854.7856 Pressure required to constrain translation vectors Tv( 33) Pressure: 0.19 GPa Tv( 34) Pressure: 0.07 GPa Tv( 35) Pressure: 0.10 GPa SCF CALCULATIONS = 15 WALL-CLOCK TIME = 3 MINUTES AND 42.475 SECONDS COMPUTATION TIME = 3 MINUTES AND 38.445 SECONDS FINAL GEOMETRY OBTAINED MERS=(1,1,1) CHARGE=0 OUTPUT THREADS=1 PM7 GRADIENTS NOTXT EF Tungsten(vi) trioxide (WO3) h=-201.4 hr=crc W -0.09713724 +1 0.01417538 +1 0.06222205 +1 W 5.46303916 +1 1.54774331 +1 -1.33873475 +1 W 0.49271498 +1 -2.66209357 +1 -2.63677287 +1 W -1.30668404 +1 -5.27370632 +1 -0.32413118 +1 W 1.70330407 +1 2.62897141 +1 -2.24963969 +1 W -3.39450293 +1 -1.87977026 +1 -3.26543683 +1 W 2.44875755 +1 -6.36258461 +1 0.58881636 +1 O -3.61426105 +1 -0.31737397 +1 -2.13738821 +1 O 5.22736784 +1 3.10843104 +1 -0.21124518 +1 O 0.09889065 +1 -1.53831820 +1 -1.08089954 +1 O 1.31747518 +1 3.74270223 +1 -0.68583186 +1 O 5.22065397 +1 0.59595707 +1 -3.03437850 +1 O -3.54682076 +1 2.19745998 +1 0.69141173 +1 O 1.22840760 +1 1.22211042 +1 -3.49998627 +1 O 0.11333813 +1 0.95354732 +1 1.76658660 +1 O -3.06460511 +1 2.14870453 +1 -1.83744569 +1 O -4.15556779 +1 -0.63525936 +1 0.61763690 +1 O -0.36816188 +1 -4.03070249 +1 -1.34240900 +1 O 0.71523419 +1 -1.25086210 +1 -3.82423920 +1 O 0.82743492 +1 1.26373741 +1 -0.96017157 +1 O -0.41286389 +1 -1.51047558 +1 1.43526692 +1 O -4.27237572 +1 -3.14055817 +1 -2.21987991 +1 O -3.01872183 +1 -0.37753571 +1 -4.64154983 +1 O -1.83177361 +1 0.40325287 +1 -0.26727957 +1 O 3.41365316 +1 2.16291928 +1 -1.88474395 +1 O -1.65554162 +1 -2.26586707 +1 -2.93754488 +1 O 0.73489246 +1 -5.91022893 +1 0.23914700 +1 O -0.44242663 +1 3.04777247 +1 -2.54869014 +1 O 1.95169101 +1 -0.61282334 +1 0.60723076 +1 O -3.04070789 +1 -4.89288639 +1 -0.65747922 +1 O 2.20095085 +1 -3.13364034 +1 -2.26393127 +1 W -3.98665665 +1 0.79048724 +1 -0.56671750 +1 Tv 7.64784784 +1 -1.86436211 +1 1.53895233 +1 Tv 2.32786564 +1 5.54828614 +1 -4.87667410 +1 Tv 0.09287097 +1 5.01948366 +1 5.65716320 +1